全文获取类型
收费全文 | 2433篇 |
免费 | 293篇 |
国内免费 | 155篇 |
专业分类
化学 | 1849篇 |
晶体学 | 23篇 |
力学 | 107篇 |
综合类 | 1篇 |
数学 | 236篇 |
物理学 | 665篇 |
出版年
2024年 | 4篇 |
2023年 | 95篇 |
2022年 | 109篇 |
2021年 | 113篇 |
2020年 | 162篇 |
2019年 | 172篇 |
2018年 | 159篇 |
2017年 | 109篇 |
2016年 | 170篇 |
2015年 | 161篇 |
2014年 | 185篇 |
2013年 | 233篇 |
2012年 | 262篇 |
2011年 | 248篇 |
2010年 | 162篇 |
2009年 | 122篇 |
2008年 | 130篇 |
2007年 | 107篇 |
2006年 | 60篇 |
2005年 | 33篇 |
2004年 | 18篇 |
2003年 | 9篇 |
2002年 | 16篇 |
2001年 | 4篇 |
2000年 | 10篇 |
1999年 | 1篇 |
1998年 | 7篇 |
1997年 | 1篇 |
1996年 | 1篇 |
1995年 | 2篇 |
1994年 | 1篇 |
1993年 | 2篇 |
1991年 | 1篇 |
1990年 | 6篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1986年 | 1篇 |
1985年 | 3篇 |
排序方式: 共有2881条查询结果,搜索用时 62 毫秒
61.
Mubashir Hussain Zhen Chen Mu Lv Jingyi Xu Xiaohan Dong Jingzhou Zhao Song Li Yan Deng Nongyue He Zhiyang Li Bin Liu 《中国化学快报》2021,31(12):3163-3167
The rapid identification of pathogens is crucial in controlling the food quality and safety. The proposed system for the rapid and label-free identification of pathogens is based on the principle of laser scattering from the bacterial microbes. The clinical prototype consists of three parts: the laser beam, photodetectors, and the data acquisition system. The bacterial testing sample was mixed with 10 mL distilled water and placed inside the machine chamber. When the bacterial microbes pass by the laser beam, the scattering of light occurs due to variation in size, shape, and morphology. Due to this reason, different types of pathogens show their unique light scattering patterns. The photo-detectors were arranged at the surroundings of the sample at different angles to collect the scattered light. The photodetectors convert the scattered light intensity into a voltage waveform. The waveform features were acquired by using the power spectral characteristics, and the dimensionality of extracted features was reduced by applying minimal-redundancy-maximal-relevance criterion (mRMR). A support vector machine (SVM) classifier was developed by training the selected power spectral features for the classification of three different bacterial microbes. The resulting average identification accuracies of E. faecalis,E. coli and S. aureus were 99%, 87%, and 94%, respectively. The overall experimental results yield a higher accuracy of 93.6%, indicating that the proposed device has the potential for label-free identification of pathogens with simplicity, rapidity, and cost-effectiveness. 相似文献
62.
Cellulose - In this study, a biomass pretreatment strategy with a recyclable cosolvent (toluene sulfonic acid/ethanol) was developed. The low boiling point solvent (78.15 °C),... 相似文献
63.
Wei Lv Chun Wang Xing-Chi Lin Xiao-Fei Mei Wen Wang E Yang Qi-Dan Ling Zheng-Huan Lin 《高分子科学》2021,39(9):1177-1184
Solid-stated smart polymers responsive to external stimuli have attracted much attention for potential application in the field of photoelectron devices, logic gates, sensor, data storage and security. However, it is a bigger challenge for polymers than that for small molecules in solid state to acquire stimuli-responsive properties, because polymers with high molecular weight are not as easy to change the packing structure as small molecules under external stimulation. Here, a D-A type alternating copolymer PTMF-o containing 3,4-bisthienylmaleimide(A unit) and fluorene(D unit) is designed and synthesized. Upon irradiation of sunlight, PTMF-o film exhibits a photo-response with the color altering from purple to colorless. It is attributed to the structure of copolymer transformed from ring-opening form(PTMF-o) to ring-closure form(PTMF-c), resulting from the oxidative photocyclization of 3,4-bisthienylmaleimide unit. Consequently, the ability of charge transfer(CT) from fluorene to 3,4-bisthienylmaleimide unit in PTMF-o can be easily weakened by light stimuli. PTMF-o film displays a WORM-type resistive storage performance for the strong CT. Interestingly, after exposure, the electrical memory behavior in situ transfers into FLASH type, due to weak CT in PTMF-c. PTMF-o film can also be employed as smart material to construct NAND and NOR logic gates by using light as input condition. The work provides a simple way to modify the electronic properties of polymers and realize stimuli-response in solid states. 相似文献
64.
冰-水界面动力学性质在冰形核、生长、表界面熔化中扮演核心角色, 长期以来一直被广泛关注. 然而, 受限水体系中冰-水界面的动力学性质却鲜有报道. 本工作利用平衡态分子动力学模拟方法和受限固-液两相平衡模拟技术, 对两种水模型(恒定偶极矩、可极化)描述的单分子层受限冰-水两相平衡体系中的一维固-液界线开展研究. 通过对一维受限冰-水界线的追踪, 计算了其热涨落波动的振幅与时间自关联函数色散谱, 进而计算一系列固-液界线动力学性质. 冰-水界线波动在短波长区域复合了快、慢两种不同时间尺度的弛豫过程, 在长波长区域则由慢弛豫过程主导. 相比块体冰-水界面体系, 以Rayleigh波为主的高频微观物理过程更多地参与了一维冰-水界线的动力学弛豫. 我们发现冰-水界线波动弛豫特征衰减时间的波矢依赖关系符合现有固-液界面动力学理论, 但一维界线弛豫的特征衰减时间比二维界面体系低了一个数量级左右. 计算了两种水模型体系冰-水界线的动力学系数, 并与块体冰-水界面比较, 发现受限冰-水(固-液)界线动力学系数远高于块体冰-水界面体系. 我们推测水分子转动自由度在受限腔中被强烈压制可能是导致受限体系超快冰-水(固-液)相变速率的主要原因. 本工作将在受限水体系超快相变(储能、传感)器件的设计工作中提供一定的理论指导意义. 相似文献
65.
Reduction of Dimerization Tendency Due to the Decrease in Hybridization Index by Inclusion of 4s and 4p Semicore States as Valence States in Mon (n=2-18) Clusters: A First-Principles Study 下载免费PDF全文
Zhao-ye Gong Zhi-qiang Sun Yan-wen Ding Shuai Zhang Zhen-long Lv Xiao-fei Wang Li-ben Li Hai-sheng Li 《化学物理学报(中文版)》2021,34(5):639-648
Owing to the unique structural, electronic, and physico-chemical properties, molybdenum clusters are expected to play an important role in future nanotechnologies. However, their ground states are still under debate. In this study, the crystal structure analysis by particle swarm optimization (CALYPSO) approach is used for the global minimum search, which is followed by first-principles calculations, to detect an obvious dimerization tendency in Mo\begin{document}$ _n $\end{document} (\begin{document}$ n $\end{document} = 2\begin{document}$ - $\end{document} 18) clusters when the 4s and 4p semicore states are not regarded as the valence states. Further, the clusters with even number of atoms are usually magic clusters with high stability. However, after including the 4s and 4p electrons as valence electrons, the dimerization tendency exhibits a drastic reduction because the average hybridization indices \begin{document}$ H_{ \rm{sp}} $\end{document} , \begin{document}$ H_{ \rm{sd}} $\end{document} , and \begin{document}$ H_{ \rm{pd}} $\end{document} are reduced significantly. Overall, this work reports new ground states of Mo\begin{document}$ _n $\end{document} (\begin{document}$ n $\end{document} = 11, 14, 15) clusters and proves that semicore states are essential for Mo\begin{document}$ _n $\end{document} 相似文献
66.
Hui Lv Prof. Qian Li Prof. Jiye Shi Prof. Chunhai Fan Prof. Fei Wang 《Chemphyschem》2021,22(12):1151-1166
The high sequence specificity and precise base complementary pairing principle of DNA provides a rich orthogonal molecular library for molecular programming, making it one of the most promising materials for developing bio-compatible intelligence. In recent years, DNA has been extensively studied and applied in the field of biological computing. Among them, the toehold-mediated strand displacement reaction (SDR) with properties including enzyme free, flexible design and precise control, have been extensively used to construct biological computing circuits. This review provides a systemic overview of SDR design principles and the applications. Strategies for designing DNA-only, enzymes-assisted, other molecules-involved and external stimuli-controlled SDRs are described. The recently realized computing functions and the application of DNA computing in other fields are introduced. Finally, the advantages and challenges of SDR-based computing are discussed. 相似文献
67.
Originating from the 1.23 V potential window of pure water, the narrow electrochemical stability window (ESW) has always been the most stubborn problem for aqueous battery systems. However, the water-in-salt system magically widens the ESW of aqueous electrolyte from 1.23 V to above 3 V by the super-concentrated LiTFSI solution. The mechanisms of widening aqueous battery ESW have been a crucial topic, in which the significant factors, including unique solid–electrolyte interface, solvation structure, and others, have been highlighted. Here, we specify the concept of ESW in detail and review the influence factors of ESW in the water-in-salt system from both thermodynamic and kinetic perspectives to explore the importance of each factor. 相似文献
68.
69.
70.